화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 기능성 고분자
제목 Reversible Optical Patterns from the Photoisomerization and Thermal Relaxation of Cyclosiloxane-Based AIEgens
초록 A cyclosiloxane-based photoisomerizable AIEgen (CSPA) was newly synthesized for reversibly switchable optical patterns. The photoisomerization of CSPA in bulk easily occurs due to flexible cyclosiloxane and enough alkyl chains. The isomerization from trans to cis form induces phase transition to isotropic, which results in changes in optical properties. Reverse isomerization of CSPA can occur by thermal annealing above 200 ℃. As a result, reversible optical patterns are successfully demonstrated by reversible isomerization behaviors of CSPA. This work was supported by Mid-Career Program (2021R1A2C2009423), and Basic Science Research Program (NRF-2019R1A6A3A13092060) funded by the Ministry of Education.
저자 구자현, 정광운
소속 전북대
키워드 Photoisomerization; Aggregation-induced emission
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