| 학회 | 한국공업화학회 |
| 학술대회 | 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 | 20권 1호 |
| 발표분야 | 환경에너지_포스터 |
| 제목 | Esterification of 5-Chloromethyl-2-furfural (CMF) and 5-Hydroxymethyl-2-furfural (HMF) into 5-Acetoxymethyl-2-furfural (AMF) by alkylammonium functionalized resin |
| 초록 | 5-Hydroxymethyl-2-furfural (HMF) is the most well-known biomass-derived platform chemical, which has the possibility to replace BTX-based aromatic compounds produced from petroleum. 5-Chloromethyl-2-furfural (CMF) has been proved to be more efficient as material for later applications. In this study, the sythesis of 5-acetoxymethyl-2-furfural (AMF) from CMF and HMF using polymer resin supported alkylammonium acetates. HMF is formed by dehydration, which have used by continuous reactor from fructose, amberlyst-15, DMSO, 1,4-dioxane. CMF is produced by biphasic continuous reactor, which have formed easily from fructose, hydrochloric acid and dichloromethane or dichloroethane. The yield of AMF reached up to 60%. |
| 저자 | 박석규1, Huynh Thanh Thien Nhan1, 김보라1, TanPhat Nguyen1, Vo Thi Hoang Anh1, 이홍식1, 김상용1, 이관영2, 조진구1 |
| 소속 | 1한국생산기술(연), 2고려대 |
| 키워드 | CMF; HMF; AMF; esterification |
