화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 고분자 구조 및 물성
제목 Phase Behavior of Poly(3-alkylthiophene)/Polystyrene Belnds
초록 Phase diagrams of poly(3-n-alkylthiopene)/polystyrene (P3AT/PS) blends having various n-alkyl side chain lengths (n = 4, 6, 8, 12) of P3AT were obtained by the turbidity measurement. All of P3AT/PS blends exhibited the upper critical solution temperature (UCST) at small molecular weights. Interestingly, as increasing the alkyl side chain length of P3AT, the immiscibility between P3AT and PS increased from n=4 to n=6 and decreased again from n=6 to n=12. Thus, P3HT/PS blend was the most immiscible in all P3AT/PS series. That was explained by Monte Carlo simulation method.
저자 이영민1, 김진곤1, Ching-I Huang2, Chiu-Han Chiou2
소속 1포항공과대, 2Institute of Polymer Science and Engineering / National Taiwan Univ.
키워드 Phase Behavior; P3AT/PS Blend; Monte Carlo Simulation
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