화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 고분자합성
제목 Micelle formation in hydrogen peroxide in emulsion polymerization
초록 Increasing hydrogen peroxide contents, Emulsion polymerization was experimented using DI Water as medium, SDS as surfactant and Styrene as monomer. After measuring contant angle of increasing SDS contents in DI Water or hydrogen peroxide, Surface tension graph was analyzed. Increasing SDS Contents in DI Water, Surface tension values decrease and is constant at a certain point. The point is CMC and this shows micelle was formed. But, Increasing SDS Contents in hydrogen peroxide, Surface tension values is almost contant. This shows micelle is not formed. As a result, we found that hydrogen peroxide disturb micelle formation. Same experiment is performed using TWEEN80 as nonionic surfactant or CTAB as cation surfactant instead of SDS as anion surfactant. Morphology of polymer particle is investigated with SEM images.
저자 이시정, 이성은, 최순자
소속 인하대
키워드 hydrogen peroxide; emulsion polymerization
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