화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.1170
발표분야 International Symposium on Display Materials and Processes
제목 New Molecular and Polymeric Materials and Fabrication Methodologies for Flexible Organic Transistors
초록 The general design and synthesis of new oligothiophenes and arenes functionalized with a variety of phenacyl, alkylcarbonyl, and perfluoroalkylcarbonyl is presented. These organic semiconductors exhibit low-lying LUMOs allowing efficient electron injection/transport. Organic field-effect transistors (OFETs) fabricated by conventional methods exhibit electron mobilities as high as 2 cm^2 V^-1 s^-1 for vapor-deposited films and 0.25 cm^2 V^-1 s^-1 for solution-cast films with current modulation > 10^8.
Furthermore, these materials are compatible with new classes of nanoscopic layer-by-layer self-assembled multilayers (SAMT) and crosslinked polymeric blend (CPB) gate dielectrics developed in our group. These dielectric materials are fabricated conveniently via solution-phase methodologies at very low temperature (< 110 °C) and exhibit very low leakage currents (< 10^-8 A cm^-2), high breakdown fields (> 3 MV cm^-1), very high capacitance values (up to 2500 nF cm^-2) and are fully compatible with both electron- and hole-transporting organic (and inorganic) semiconductors. OFETs and complementary inverter devices operating at very low voltages have been fabricated. Finally, a new methodology for device fabrication is presented.
저자 Antonio Facchetti
소속 Northwestern Univ.
키워드 OFET; SAMT; CPB; Gate Dielectrics
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