| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of thermo responsive supramolecular poly(N-isopropylacrylamide)-b-poly(D, L-lactide) pseudo-block copolymer |
| 초록 |
In the present study, thermo responsive a pseudo-block copolymer was prepared poly(N-isopropylacrylamide) (PNIPAM) as the shell and poly(DL-lactide) (PDLLA) as the core were prepared from β-cyclodextrin terminated PNIPAM and adamantine (AD)-terminated PDLLA, through host-guest interaction. Initially, the hydrophilic polymer PNIPAM was synthesized using RAFT polymerization that was further linked to N3-β-CD through click reaction. In parallel, AD-PDLLA was synthesized using ring opening polymerization (ROP). The synthesized polymers were characterized using 1H NMR, GPC and FTIR. Subsequently, the formation of a pseudo-block copolymer via inclusion complexation between β-CD core and AD-moiety were confirmed by 2D-NOESY NMR. |
| 저자 |
최원태, Kalyan Ramesh, Anugrah Daru Seto Bagus, 임권택
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| 소속 |
부경대 |
| 키워드 |
: RAFT polymerization; ROP polymerization; Thermo-responsive micelles; Pseudo-block copolymer; Poly(N-isopropylacrylamide)
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| E-Mail |
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