학회 |
한국화학공학회 |
학술대회 |
2015년 가을 (10/21 ~ 10/23, 일산 KINTEX) |
권호 |
21권 2호, p.1965 |
발표분야 |
유동층 |
제목 |
Reaction kinetics for the preparation of LaMnO3 powder by means of self-propagating reaction |
초록 |
LaMnO3 has been recognized as the host material for the solid oxide fuel cells (SOFC) which exhibited their potential use as clean and efficient powder-generating devices. The reaction for the preparation of LaMnO3 powder was analyzed by using TGA to predict the preparation kinetics. The extremely rapid weight loss giving rise to a very sharp exothermicity indicated that the reaction for the preparation of LaMnO3 powder from the precursors with Citric acid was the self-propagating reaction. The reaction order, activation energy during the non-isothermal reaction were predicted by adopting the Friedman, Ozawa-Flynn-wall and Vyazovkin methods. The optimum ratio of C/N was 0.8 for the optimum performance of the self-propagating auto-ignition reaction to prepare LaMnO3 powder within this experimental condition. |
저자 |
강 용, 유동준, 임대호, 이정훈, 전종설
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소속 |
충남대 |
키워드 |
LaMnO3 powder; self-propagating reaction; kinetics; Non-isothermal analysis; Citric acid
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E-Mail |
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원문파일 |
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