| 초록 |
Polymer electrolyte construction and characterization studies of phenol and imidazole complex systems have been carried out. The complexes were prepared by simple melt blending at several stoichiometric ratios, x (molar ratio of the monomer repeat units). The complexes having groups of redox-active site as ligands were demonstrated to perform multistep proton transfer (PT), electron transfer (ET), and proton-coupled electron transfer (PCET) processes. Thermodynamic parameters including pKa and bond dissociation energy (BDE) of multistep PCET processes in acetonitrile (MeCN) were determined for these complexes. The redox-active process of electrolyte, was occured in the polymer networks during complexation. The temperature and pH optimization, operational stability, and ionic conductivity of the polymer electrolyte were also examined. |
