화학공학소재연구정보센터
학회 한국재료학회
학술대회 2019년 봄 (05/15 ~ 05/17, 평창 알펜시아 리조트)
권호 25권 1호
발표분야 C. 에너지 재료 분과
제목 Synthesis and Evaluation of PVA-CN Additives for High Temperature Stability of Secondary Battery Electrolyte
초록 Recently liquid electrolyte having excellent ion-conductivity and high electrochemical stability has been used for the secondary battery. But it has been reported there was a serious problem in the high temperature stability. In this research, the development of PVA-CN additive which is used in secondary battery electrolyte was carried out with 2 steps; the 1st step was the dissolution of PVA raw materials and the 2nd step was the synthesis of PVA-CN. The thermal property of the prepared additive was quantitatively analyzed using TGA. The significantly improved thermal stability of the electrolyte containing PVA-CN was also confirmed by monitoring swelling behavior at high temperature, i.e. 29% less swelling effect, although they exhibited slightly lower ion conductivity. This finding clearly suggests the possibility of preventing the swelling issue at the high temperature which is the main cause of dangerous accidents from secondary batteries.
저자 Jian Hou1, 채지훈2
소속 1Department of Chemical Engineering, 2Zibo Vocational Institute
키워드 PVA; Secondary Battery; High Temperature Stability; composite
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