학회 |
한국고분자학회 |
학술대회 |
2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
권호 |
47권 1호 |
발표분야 |
콜로이드 및 분자조립 부문위원회 |
제목 |
Fast and Large Motion of Self-Oscillating Gels with Phase-separated Structures |
초록 |
Unlike conventional stimuli-responsive gels, self-oscillating gels can spontaneously repeat swelling/deswelling without external stimuli. Due to these characteristics, they can be utilized as biomimetic materials showing heartbeat-like motions. However, there are limitations, such as small and slow changes in the degree of swelling/deswelling. Here, we designed novel self-oscillating gels showing fast and large deformation by tuning the internal structure of the gels. Using the collapsed form of poly(N-isopropylacrylamide) in a salt solution, it is possible to synthesize the phase-separated network showing ultrafast and large shrinkage. Furthermore, we incorporated negatively charged nanogels to obtain fast re-swelling behavior. These novel self-oscillating gels showed overwhelmingly fast and large motions under the condition of the Belousov-Zhabotinsky (BZ) reaction. This presentation will discuss the synthetic strategy of self-oscillating gels and their improved performance. |
저자 |
최재원1, 정태훈1, Ryo Yoshida2, 김연수1
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소속 |
1포항공과대, 2The Univ. of Tokyo |
키워드 |
Hydrogel; Actuator; Self-Oscillating; Phase-separated; Belousov-Zhabotinsky; BZ reaction
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E-Mail |
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