| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis and characterization of poly (arylene ether sulfone) membrane for alkaline membrane fuel cell. |
| 초록 |
Alkaline membrane fuel cell (AMFC) has received considerable attention due to fast oxygen reduction reaction, which can lower amount of platinum catalyst loading. However, available anion exchange membranes (AEM) are limited for wide researches and application of fuel cell. In this study, anionic poly(arylene ethers sulfone)(SPES) multi-block copolymer membranes with trimethylammonium group were synthesized via nucleophilic aromatic substitution, followed by chloromethylation and quaternization. Length of hydrophobic and hydrophilic blocks was controlled to have different ion exchange capacity. Their chemical structures and degree of chloromethylation were characterized by NMR. Other physical properties such as alkaline stability, hydroxide conductivity and water uptake were investigated. These new ionic block copolymer membrane can be a candidate as AEM for AMFC. |
| 저자 |
배병찬1, 이소정2, 김은영1
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| 소속 |
1UST / 한국에너지기술(연), 2한국에너지기술(연) |
| 키워드 |
Alkaline membrane fuel cell (AMFC); anion exchange membranes (AEM); poly(arylene ethers sulfone)(SPES)
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| E-Mail |
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