| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Polymerization of an Acetylene Derivative with Bulky Hydroxy Functional Groups by Transition Metal Catalysts |
| 초록 |
The polymerization of acetylene derivative with hydroxy functional groups are of interest because of their unique structures and facile modification of hydroxy groups with other interesting functional groups. Here, a new conjugated polymer with bulky substituent containing two hydroxy groups was synthesized and characterized. Transition metal-catalyzed polymerization of ethynylestradiols proceeded in mild manner to give moderate yield of polymer. The resulting materials were completely soluble in organic solvents and well processible. The photoluminescence peak was located at 410 nm corresponding to the photon energy of 3.03 eV. The HOMO energy level calculated from electrochemical measurements was 5.47 eV. |
| 저자 |
제갈영순1, 진성호2, 박종욱3, 임권택4
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| 소속 |
1경일대, 2부산대, 3가톨릭대, 4부경대 |
| 키워드 |
polyacetylene; catalyst; hydroxy group; characterization; photoluminescence
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| E-Mail |
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