화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.185
발표분야 미립자공학
제목 Preparation and Characterization of Cu/Pt/BEA Catalyst for Low Temperature CO Oxidation
초록 The low temperature CO oxidation over Pt-based bimetallic catalysts was investigated. Various additives such as Ni, Cu, Pd, Ag and Au were added to the Pt/BEA catalyst by an ion-exchange method and the addition of Cu to the calcined Pt/BEA catalyst was found to remarkably improve the catalytic performance. A calcination step for the Pt/BEA before Cu ion-exchange was especially important in forming the active phases for CO oxidation. XRD results indicated that the metallic Pt was not considered to be related to the active site for CO oxidation. Moreover, interactions between Pt and Cu on the Cu/Pt*/BEA catalyst could be confirmed by CO-TPD. Pt was found to be an active component for CO oxidation, but is easily deactivated by the adsorption of CO molecules. It is thought that Cu, interacting with Pt, plays an important role in preventing the deactivation of Pt.
저자 홍승태1, 박달령2, 유승준3, 박형상1, Masakazu Anpo4
소속 1서강대, 2한국가스공사, 3서남대, 4오사카부립대
키워드 CO oxidation; Low temperature; Cu/Pt/BEA catalyst; Calcination effect
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