| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
석유화학.윤활유_포스터 |
| 제목 |
Roles of Al promoter on mesoporous Rh-mpg-C3N4 for a liquid-phase carbonylation of methanol |
| 초록 |
The positive roles Al promoter on the heterogeneous Rh-incorporated mesoporous graphitic carbon nitride (Rh-mpg-C3N4) were investigated for a liquid-phase carbonylation of methanol to acetic acid (AA) to compete with commercialized Rh-based homogeneous catalysts under the reaction conditions of 463K and CO pressure of 4.0 MPa for reaction duration of 1h. The Al-modified Rh-mpg-C3N4 at its optimal amount below 2.5 wt% showed a higher AA yield above 60% compared to the unmodified Rh-mpg-C3N4. A highly dispersed Lewis acidic Al species on the Rh-mpg-C3N4 increased the reverse esterification reaction rate of methyl acetate (MA) intermediate to AA, which has been known to be more favorable reaction on acidic sites through hydrolysis reaction of AA. |
| 저자 |
김다미, 배종욱
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| 소속 |
성균관대 |
| 키워드 |
Liquid-phase carbonylation; Rh-based heterogeneous catalyst; Rh-mpg-C3N4; Graphitic carbon nitride; Acetic acid
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| E-Mail |
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