화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-콜로이드·계면화학
제목 Optimization of chemical separation of Pu, Am with UTEVA resin for plutonium age dating purpose by using MC-ICP-MS
초록 The age of a Pu material can determine using several chronometers, such as 241Am/241Pu, 234U/238Pu, 235U/239Pu, 236U/240Pu or 238U/242Pu. 241Am/241Pu is one of the most commonly used isotope pair due to the relatively rapid ingrowth of 241Am and availability of high-precision. For determining highly accurate and precise 241Am/241Pu ratio, Am has to be separated and purified to remove interfering species from plutonium samples. For this purpose, we adopted relatively simple and effective chemical separation method based on UTEVA resin. When the sample solution of 5 M HNO3 is loaded on the UTEVA resin column, Pu adsorbs on the resin, and Am passes through the column. Based on this method, we optimized separation condition. In order to decide the optimal elution volume, the elution curve was produced from optimized separation schemes. In the future, the optimized method in this study will be applied with plutonium sample for plutonium age dating.
저자 박난희, 이치규
소속 한국원자력(연)
키워드 Plutonium age dating; chemical separation; MC-ICP-MS
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