화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX)
권호 15권 2호, p.1935
발표분야 환경
제목 Immobilization of copper in aqueous solution by un-calcined sodium exchanged and acid modified montmorillonite
초록 The removal of Cu2+ from aqueous solution by batch adsorption technique using un-calcined sodium exchanged (Na-MMT) and acid modified montmorillonite (A-MMT) was investigated. The sensitivity of the Cu2+ removal process using Na-MMT and A-MMT was highly influenced by pH, initial Cu2+ concentration, reaction time and temperature. The rate kinetics for the adsorption of Cu2+ onto Na-MMT and A-MMT followed the pseudo-second-order kinetic model for the range of concentrations studied. Isotherm models were applied. The Redlich-Peterson and Dubinin-Radushkevich model fit best the equilibrium data of Na-MMT and A-MMT respectively. The thermodynamic parameters, such as Go, Ho, and So were also determined and evaluated. Na-MMT has a better adsorption potential than A-MMT. The potentials of both Na-MMT and A-MMT can be explored as effective adsorbents for the removal of toxic heavy metals in industrial effluents.
저자 김동수, Christianah Olakitan Ijagbemi
소속 이화여자대
키워드 Adsorption; Copper; Na-montmorillonite; A-montmorillonite; Isotherm; Kinetics
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