| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Increased possibility of galvanostatic electrolysis in ionic liquid by dissolved metal complex and suitable electrode pair |
| 초록 |
Electrode dissolution in ionic liquid medium during constant current electrolysis restricts to use in many industrial applications. Keeping this in mind, use of metal complex in ionic liquid can be a good choice to control the electrode dissolution by control the potential window. In the present work, constant current electrolysis were performed in presence and absence of Co(CN)53- to understand the electrode dissolution effect in 1-Butyl-3 Methylimidazolium HexafluoroPhosphate (BMIHFP) ionic liquid. Initial CV analysis in presence of Co(CN)53- using Pt electrode found minimize the BMIHFP potential window. Constant current electrolysis was performed with and without Co(CN)53- using different pairs of electrodes such as Pt-Pt, Graphite-PT, Graphite-Graphite, Graphite-DSA, Graphite-BDD and monitored the electrode dissolution by UV-Visible and ICP-OES. Graphite-BDD electrodes pair found suitable pair of electrodes. |
| 저자 |
G. MUTHURAMAN, Kannan Karunakaran, 문일식
|
| 소속 |
순천대 |
| 키워드 |
Homogeneous mediator; Co(CN)53-; Ionic liquid; Cell potential; Electrode dissolution.
|
| E-Mail |
|
