| 학회 |
한국공업화학회 |
| 학술대회 |
2007년 가을 (11/02 ~ 11/03, 한경대학교) |
| 권호 |
11권 2호 |
| 발표분야 |
우수논문(구두) |
| 제목 |
Highly enantioselective ring opening of epoxides catalyzed by Heterobimetallic Schiff-Bases containing transition metal atoms |
| 초록 |
An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles (such as: H2O, Phenols, and CO2 etc.) to produce valuable chiral building blocks in enantio-riched forms. The newly synthesized heterobimetallic chiral Co (salen) complexes exhibited excellent enantioselectivity up to ＞98% ee in good yields. |
| 저자 |
라울, 김건중
|
| 소속 |
인하대 |
| 키워드 |
Heterobimetallic catalyst; Chiral building blocks; Cobalt salen complexes; kinetic resolution; Asymmetric catalysis
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| E-Mail |
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