| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
콜로이드·계면화학_포스터 |
| 제목 |
Modulator-Assisted Synthesis of Zinc-based Coordination Polymer Nanocubes and Post-Modification through Secondary Metal Ion Decoration |
| 초록 |
Coordination polymer particles (so called metal organic frameworks) are generally constructed through the coordination-driven assembly of metal ions or clusters with multitopic organic linkers. Their structural tailorability, high degree of porosity, and diverse chemical functionalities render them promising candidates for numerous potential applications. In this work, we report a shape-controllable synthetic protocol for Zinc-based coordination polymer nanocubes (Zn-CPNs). In the synthesis, 2,6-bis[(4-carboxyanilino)carbonyl] pyridine ([N3]) ligand is employed as an efficient shape-directing modulator to control the size and shape of Zn-CPNs. The [N3] ligand provides plenty of metal binding sites and beneficial defects in the structure of Zn-CPNs, which is suitable for the coordination of other functional metals. The secondary metal ion-modified Zn-CPNs exhibit improved catalytic activities. |
| 저자 |
TRANMINHNGOC, MAIDUYHIEN, 유효종
|
| 소속 |
한림대 |
| 키워드 |
Coordination polymer particles; coordinatively unsaturated sites; Zinc-based coordination polymer nanocubes
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| E-Mail |
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