| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Azide-alkyne click reaction of crossinking 2,2-dinitropropyl propiolate ester and azido copolyether polyol. |
| 초록 |
2,2-Dinitropropyl propiolate ester(DNPP) was provided by esterification of propiolic acid and DNP-OH. Copolyether polyol could be synthesized by Cu(Ⅰ)-catalyzed 1,3-dipolar cycloaddition between the poly(GAP-co-THF) and DNPP at [azide]/[alkyne]/ [CuSO45H2O]/[Na ascrobate]=1/1/0.1/0.5. The triazole with high heat of formation and triazole based salts are promising as energetic materials. The structure and the composition of synthesized copolymers have been characterized by 1H-NMR and GPC. |
| 저자 |
배인주, 박종혁, 이관규, 이혜림, 이범재
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| 소속 |
충남대 |
| 키워드 |
Esterification; Energetic material; Click chemistry; copper(I)-catalyzed 1; 3-dipolar cycloaddition; GAP; poly(GA-THF)
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| E-Mail |
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