화학공학소재연구정보센터
학회 한국재료학회
학술대회 2014년 봄 (05/15 ~ 05/16, 창원컨벤션센터)
권호 20권 1호
발표분야 A. 전자/반도체 재료(Electronic and Semiconductor Materials)
제목 Dependence of Microwave Dielectric Properties of (Mg0.95Ni0.05)(Ti1-xSnx)O3 Ceramics on Structural Characteristics
초록 Relationship between crystal structural characteristics and microwave dielectric properties of (Mg0.95Ni0.05)(Ti1-xSnx)O3 (MNTS, 0 ≤ x ≤ 0.25) ceramics were investigated. With increase of Sn4+ substitution up to 0.15, the single phase with ilmenite structure was observed, while the secondary phase of SnO2 was confirmed for the specimens with further Sn4+ substitution. The grain size of the specimens decreased and the number of pores increased with increasing Sn4+ substitution. However, the quality factor (Qf) of the MNTS showed improved value with increasing Sn4+ substitution. For the specimens with single phase of ilmenite, the Qf of the specimens significantly depended on the B-site bond valence of the specimens. The dielectric constants (K) of the specimens decreased with increase of Sn4+ substitution due to the lower dielectric polarizability of Sn4+ than Ti4+. The temperature coefficient of resonant frequency (TCF) of the specimens decreased with Sn4+ substitution due to the decrease of octahedral distortion of the specimens.
저자 Young Jun Eoh1, Hyun Jin Jo2, Eung Soo Kim3
소속 1Department of Materials Engineering, 2Kyonggi Univ., 3Suwon
키워드 Microwave Dielectric Properties; Structural Characteristics
E-Mail