| 학회 |
한국재료학회 |
| 학술대회 |
2017년 봄 (05/17 ~ 05/19, 목포 현대호텔) |
| 권호 |
23권 1호 |
| 발표분야 |
C. 에너지 재료 분과 |
| 제목 |
Cu2SnS3 (CTS) Thin Films Solar Cells Formed By Rapid Thermal Annealing of Direct Precursor Solution Coatings |
| 초록 |
A simple and eco-friendly method of solution processing of Cu2SnS3 (CTS) absorbers using an aqueous precursor solution is presented. The precursor solution was prepared by mixing metal salts into a mixture of water and ethanol (5:1) with monoethanolamine as an additive at room temperature. Nearly carbon-free CTS films were formed by multi-spin coating the precursor solution and heat treating in air followed by rapid thermal annealing in sulfur vapor at various temperatures. Exploring the role of the annealing temperature in the phase, composition and morphological evolution is essential for obtaining highly efficient CTS-based thin film solar cells (TFSCs). Investigations of CTS absorber layers annealed at various temperatures revealed that the annealing temperature plays an important role in further improving device properties and efficiency. A substantial improvement in device efficiency occurred only at the critical annealing temperature, which produces a compact and void-free microstructure with large grains and high crystallinity as a pure-phase absorber layer. Finally, at an annealing temperature of 600 °C, the CTS thin film exhibited structural, compositional and microstructural anisotropy, yielding a reproducible power conversion efficiency of 1.80 %. Interestingly, CTS TFSCs exhibited good stability when stored in an air atmosphere without encapsulation at room temperature for 3 months, whereas the performance degraded slightly when subjected to accelerated aging at 80 °C for 100 hours under normal laboratory conditions. |
| 저자 |
Umesh P. Suryawanshi1, Jin Hyeok Kim2
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| 소속 |
1Optoelectronics Convergence Research Center, 2Department of Materials Science and Engineering Chonnam National Univ. |
| 키워드 |
<P>Cu<SUB>2</SUB>SnS<SUB>3</SUB>; CTS; Solar cell</P>
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| E-Mail |
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