| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Electro-Optical and Electrochemical Properties of Poly(diethyl dipropargylmalonate) |
| 초록 |
The cyclopolymerization of nonconjugated diynes were extensively investigated in an attempt to prepare the polymer that would contain alternating double and single bonds along the polymer main chain with a cyclic recurring unit. Here, the poly(diethyl dipropargylmalonate) was prepared by modified palladium chlorides. The electro-optical and electrochemical properties of poly(diethyl dipropargylmalonate) were measured and discussed. The cyclovoltamograms of the polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. It was found that the kinetics of the redox process of polymer might be mainly controlled by the electron transfer process. The photoluminescence peak of polymer was observed at 543 nm, which is corresponded to the photon energy of 2.51 eV. |
| 저자 |
박종욱1, 박영일2, 임권택3, 심상연4, 진성호5, 제갈영순6, 류재민1
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| 소속 |
1가톨릭대, 2한국화학(연), 3부경대, 4강릉원주대, 5부산대, 6경일대 |
| 키워드 |
Conjugated polymer; cyclopolymerization; diethyl dipropargylmalonate; PL; CV
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| E-Mail |
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