| 학회 |
한국공업화학회 |
| 학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
26권 1호 |
| 발표분야 |
[특별세션] 탄소중립지향 이산화탄소 기반 화학산업을 위한 기술(CtoX 기술개발연구단) |
| 제목 |
Catalytic CO2/prolylene oxide copolymerization |
| 초록 |
Double metal cyanide complex (DMC) prepared by salt metathesis reaction of K3Co(CN)6 with ZnCl2 is commercially used in propylene oxide (PO) homopolymerization, which also shows activity in PO/CO2 copolymerization though CO2 insertion is not full; fraction of carbonate linkage to ether linkage (FCO2) fluctuates in a wide range (10-60 mol%) depending on the preparation method and conditions. Preparation of the DMC catalyst is somewhat tedious, requiring many times uneasy washing process. In this work, we disclose a preparative scale (100 g scale) synthesis of H3Co(CN)6 of which structure was elucidated by X-ray crystallography. The DMC catalyst prepared with H3Co(CN)6 yielded polymers with high carbonate linkage fraction (FCO2 0.48-0.66, depending on CO2 pressure). |
| 저자 |
이분열 |
| 소속 |
아주대 |
| 키워드 |
CO2 utilization; copolymerization; epoxide; catalyst
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| E-Mail |
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