화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Synthesis of Silica-γ-MPS on polymer electrolyte membrane from sulfonation of copolymer of alpha methyl styrene and acrylonitrile (α-SAN) for direct methanol fuel cell (DMFC)
초록 DMFC has many strong points such as volume energy density, stability of fuel storage and easy transportation. For the reason why methanol is supplied at anode ditectly, it has not only simple system of fuel supply but whole system device like portable small power supply device. Moreover, it is one of the fuel cells which are eco-friendly. The important part of DMFCs is the polymer electrolyte membrane. These days, it is Nafion that is used very universally. Though Nafion has excellent conductivity, it has a little expensive. So, this study shows that it is made by copolymerization of the alpha methyl styrene more oxidatively stable than polystyrene and the acrylonitrile which has mechanical and chemical stability. Afterwards, polymer copolymerized is sulfonated in order to improve the conductivity. In addition, by using the silane coupling agent, it is expected to have higher conductivity than Nafion at the polymer electrolyte membrane
저자 권혁중, 김창근
소속 중앙대
키워드 DMFC; membrane; conductivity
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