| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
[석유화학·재생연료] 바이오원유를 활용한 그린 바이오에너지 및 바이오화학소재 개발 |
| 제목 |
Upgrading bio-oil model compounds over bifunctional Ru/HZSM-5 catalysts |
| 초록 |
Hydrodeoxygenation(HDO) of vanillin as a bio-oil model compound was performed using bifunctional Ru loaded HZSM-5 catalysts with different metal loadings and Si/Al2 ratios in n-octane/water biphasic system. Both the reaction pathway and product distribution were influenced by the metal/acid balance of the catalysts. Higher metal/acid ratio promoted Caryl-C cleavage reaction, resulting in the increased yield of cyclohexane. Synergetic effect of metal and acid sites was observed in the bifunctional catalyst, attaining as high as 40-fold increase of metal efficiency in the ring hydrogenation reaction, compared to lone metal site catalyst. The effect of solvent composition was evaluated, revealing that the presence of water promoted the overall HDO reaction. By balancing metal/acid and introducing appropriate solvent system, efficient catalytic system that minimized carbon loss and improved metal efficiency for vanillin HDO was obtained. |
| 저자 |
김도희 |
| 소속 |
서울대 |
| 키워드 |
biooil; Ru/ZSM-5; hydrogenation; deoxygenation; bifunctional
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| E-Mail |
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