학회 | 한국공업화학회 |
학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
권호 | 26권 1호 |
발표분야 | 포스터-디스플레이 |
제목 | Synthesis and Electrochemical property of Halogenated Napthalocyanine and Quinoxaline fused phthalocyanine |
초록 | Naphthalocyanines (NPcs) and quinoxaline fused phthalocyanines (QPcs) of similar structure are macrocyclic molecules containing 18 delocalized π-electrons. They exhibit excellent thermal and chemical stability with high tinctorial strength. They have long been used as pigments, and recently their applications have been expanded to the fields of electronics, optoelectronics, and electrochemistry. Their characteristic can be readily modified through peripheral transformation and substitution of the central metal. Here in this poster, we present the synthetic, optical, and electrochemical properties of NPcs and QPcs exhibiting near-infrared absorbing behaviors. These NPc and QPc compounds are newly synthesized by placing halogen elements to the surrounding aromatic ring. The structure was thoroughly confirmed by NMR and MALDI-ToF analysis. Optical, electrochemical, and thermal properties are confirmed through UV-Vis spectra, cyclic voltammetry, and TGA, respectively, measurements. |
저자 | 장재웅, 박세정, 박종승 |
소속 | 부산대 |
키워드 | Naphthalocyanines; Quinoxaline fused phthalocyanines; NIR absorption; Halogen element |