화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.2446
발표분야 배성열 교수 정년기념 심포지엄(분리기술부문위원회 주제별 심포지엄)
제목 Enthalpy of Gas Hydrate Formation for Mixed Gas Hydrates
초록 Formation enthalpy of gas hydrates has been calculated using Clausius-Clapeyron equation from temperature pressure relation for incipient hydrate formation in mono variant single guest system. For mixed guest systems, however, cavity occupation of different guest molecules introduces additional degree of freedom and use of Clausius-Clapeyron introduces uncertainties. In the present paper a method was developed for the calculation of formation enthalpy of mixed guest hydrates using method and information for phase equilibrium calculation with van der Waals and Platteeuw model for gas hydrate phase and equation of state model for fluid phase. Calculated values were found in acceptable agreements with data.
저자 이철수, 강정원
소속 고려대
키워드 Enthalpy of Gas Hydrate Formation for Mixed Gas Hydrates
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