화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2003년 가을 (10/10 ~ 10/11, 부경대학교)
권호 28권 2호, p.131
발표분야 고분자 가공/블렌드
제목 Surface Characteristics and Dyeability of LDPE Film Produced by Mixtured Fluorination
초록 In this work, the effect of oxyfluorination on dyeability of low-density polyethylene (LDPE) film was studied in terms of surface analysis and contact angle measurements. The compositions of a mixtured F2-O2 gas were varied within 80-0, 70-10, 60-20, 40-40, and 10-70 by pressure ratio. Surface characteristics, including the functional groups and wettability of the LDPE film were confirmed by FTIR-ATR, XPS, and contact angle analyses. As a result, the oxyfluorinated LDPE film led to a decrease in water and diiodomethane angles, mainly due to the increase of oxygen functional groups and to the decrease of C-F groups with the oxygen pressure. From the dyeability tests, it was found that the oxyfluorination played an important role in the wettabilty for dispersive and basic dyeing agents. Consequently, the mixtured fluorine treatment on the LDPE film was a suitable method for modifying the hydrocabonaceous polymer surfaces.
저자 신준식1, 박수진1, 송시용1, 최길영1, 이종문2
소속 1한국화학(연), 2전북대
키워드 contact angle; dyeability; wettability; oxyfluorination; low-density polyethylene
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