초록 |
Owing to the environmental and economic problems arising from fly ash (FA), there have been various ongoing efforts over the past decades to find a use for it. Among the various applications of FA, its use as a filler in polymer composites has gained much attention. However, most studies have applied FA as a semi-reinforcing filler, which only marginally improves mechanical properties arising from the poor surface wettability of FA with polymer matrices. To solve this problem and to explore new applications, FA was carbonated by bubbling CO2 in water. The carbonated FA was adopted as a fire-proofing filler in silicone rubber and polypropylene. The surface properties and compositional changes of FA by carbonation were thoroughly examined. Mechanical and thermal properties of carbonated FA-filled polymer composites were evaluated and the interaction between the filler and matrix was calculated using DFT calculation. |