화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔)
권호 13권 1호, p.805
발표분야 열역학
제목 Isothermal vapor-liquid equilibrium for the ternary mixtures of diisopropyl ether(DIPE) + ethanol + iso-octane at 333.15K
초록 Thermodynamic data at various T, P conditions are needed for chemical process modeling and the development of parameters for thermodynamic models. Recently some oxygen contained ether compounds are considered as gasoline additives. However, the phase equilibria and mixing properties for ETBE, TAME, IPE are very few compare to those of MTBE.
In this work, isothermal vapor-liquid equilibrium(VLE) at 333.15 K for the ternary sistems of di-iso propyl ether(DIPE) + ethanol + iso-octane were measured with the help of headspace gas chromatography(HSGC). The experimental VLE data were correlated with three gE model equations of Wilson, NRTL and UNIQUAC. All the measured data in this work showed good agreement with the calculated values.
저자 황인찬, 박소진, 한규진, 곽해연
소속 충남대
키워드 VLE; DIPE; TERNARY SYSTEMS; GE-MODEL
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