| 학회 |
한국화학공학회 |
| 학술대회 |
2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 |
12권 1호, p.292 |
| 발표분야 |
분리기술 |
| 제목 |
Adsorption Characteristics of Chlorinated Organic Compounds onto Activated Carbon |
| 초록 |
This study investigated the characteristics of adsorption and separation for P-CPA, MCPA, and 2,4,5-T, from the aqueous solution onto the granular activated carbon (GAC). Adsorption equilibrium capacities of the Phenoxacetic herbicides increased with decreasing pH and temperature of the solution on the GAC. The adsorption equilibrium isotherm of P-CPA, MCPA, and 2,4,5-T was well represented by Sips equation. Kinetic parameters were measured in a batch adsorber to analyze the adsorption rates of the Phenoxacetic herbicides. The internal diffusion coefficient of the Phenoxacetic herbicides in intraparticle were determined by comparing the experimental concentration curves with those predicted from the surface diffusion model (SDM) and pore diffusion model (PDM). The internal diffusion of the Phenoxacetic herbicides in intraparticles was explained by PDM. The linear driving force approximation (LDFA) model was used to simulate the isothermal adsorption behavior of the Phenoxacetic herbicides in a fixed bed adsorber and successfully predicted. |
| 저자 |
김태영1, 박경희1, 박기민1, 김승재1, 김환범2, 서숭혁3, 조성용1
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| 소속 |
1전남대, 2전라남도 보건(연), 3계명대 |
| 키워드 |
Adsorption; P-CPA; MPCA; 2; 4; 5-T; Activated Carbon
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| E-Mail |
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| 원문파일 |
초록 보기 |
