화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자가공/복합재료-나노카본 고분자 복합필름
제목 PVDF-TrFE Actuator with Methacrylate Elastomer
초록 Elastomeric Methacrylate based triblock copolymers [Poly(methylmethacrylate-b-dodecylmethacrylate-b-methylmethacrylate)](PMDM) were prepared by ruthenium catalyst based atom transfer radical polymerization (ATRP). Obtained series of the PMDM copolymers with different molecular weights and weight fractions showed well-controlled polydispersity (PDI≤1.2). These elastomeric PMDM copolymers were then mixed with poly(vinylidenefluoride-co-trifluoroethylene) (PVDF-TrFE) in THF and then film-casted at RT. The PMDM was homogeneously dispersed into PVDF-TrFE, because of high compatibility of PMMA to PVDF-TrFE to give well-defined high ordered structures, which were confirmed by SAXS and AFM. Blended PMV films with using carbon grease as an electrode were carried out measuring the displacement of their thickness strain depending on electric charge. As a result of that, we obtained interesting thickness-strain displacement (Sz>7%) overcoming the PVDF-TrFE (65/35) limited strain range (Sz<1%).
저자 조계룡1, 곽희라2, 구종민1, 홍순만2, 황승상1, 백경열2
소속 1Nanohybrids Center, 2Korea Institute of Science and Technology
키워드 PVDF-TrFE; Actuator; Elastomer
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