화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 고분자가공/복합재료
제목 Synthesis and electrochemical performance of Li4Ti5O12/PEDOT:PSS for lithium ion battery
초록 We prepared Li4Ti5O12 by one-step solid-state carbon thermal reduction reaction. Samples of Li4Ti5O12 are synthesized with different content of PEDOT:PSS. The presence of PEDOT:PSS act as reductant. The formation mechanism of Li4Ti5O12 in the presence of carbon (PEDOT:PSS) was investigated. Moreover, the effect of Ti3+ on the electrochemical performance of the Li4Ti5O12 has been investigated systematically. Among all samples, the sample with 2% PEDOT:PSS additive exhibited the highest discharge capacity and best cycling stability. Our findings reveal that the surface modification with PEDOT:PSS can improve the electrical conductivity and Li+ diffusion coefficient and improve rate capacity and cycling stability significantly.
저자 Guijun Yang, 박수진
소속 인하대
키워드 formation mechanism; Li4Ti5O12; pedot:pss; mixed Ti valence; electrochemical performance.
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