학회 | 한국화학공학회 |
학술대회 | 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
권호 | 16권 2호, p.1899 |
발표분야 | 열역학 |
제목 | Measurement and Thermodynamic Correlation of Phase Equilibria of HI+H2O+I2 Systemfor separation of I2 from HIx Mixture by Crystallization |
초록 | SI cycle is the thermo-chemical water splitting process using sulfur and iodine and consists of a Bunsen reaction, sulfuric acid decomposition and HI decomposition. This process is most attractive in aspect of green technology and cost savings by recycling chemical elements in net reactions and reusing heat from nuclear power plants. HI decomposition is the key step in the cycle and the reaction efficiency can be improved by the separation of iodine. The measurement and modeling of solid-liquid phase equilibrium of hydrogen iodide + iodine + water system for separation process by crystallization are important but challenging. In this work, solubility of iodine in HI acid of various concentrations at 298K-360K are measured and correlated using NRTL and UVa model. |
저자 | 허자영1, 강정원1, Su Yong Han2 |
소속 | 1고려대, 2Sandy spring friends school |
키워드 | Hydrogen Produnction; SI cycle; Iodine; HIx mixture |
원문파일 | 초록 보기 |