| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Preparation of nano-sized gold particles stabilized α,ω-heterobifunctional PEOs |
| 초록 |
Functionalized polymers have been used for preparation of nano-sized transition metals or metal oxides. In this respect, we synthesized α,ω-heterotelechelic poly(ethylene oxide) via anionic mechanism. After complete polymerization of ethylene oxide using potassium azidopropanate in THF, purified propylene sulfide was delivered into the reactor under high vacuum. The resulting α-azido-ω-thiolated PEO was used to prepare the gold nano particles. Practically, to get azide-funtionalized gold nanoparticles, gold nanoparticles were prepared by using the PEO-based bifunctionalized polymer was employed bearing the chain-end thiolated group with HAuCl4 in water at 60°C, followed by reduction using NaBH4. In this presentation, the preliminary results will be discussed. |
| 저자 |
이재혁, 김윤, 양세라, 연규상, 김성우, 이유라, 시디크아부바카, 강호정, 이재열, 김정안
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| 소속 |
경희대 |
| 키워드 |
living polymerization; heterobifunctional; PEO
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| E-Mail |
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