화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-콜로이드·계면화학
제목 Recent Advances in Multi-Nuclear-Cluster-Based Heteroleptic  Multiple-Stranded Metallosupramolecules 
초록 Systematic combination of well-defined coordination spheres and geometric properties of multiple types of ligands (heteroleptic) are key approaches in the synthesis of a wide spectrum of discrete metallosupramolecules. Such heteroleptic molecular architectures are expected to afford advanced utility in a variety of applications. Recent advances in the development of multi-nuclear-cluster-based heteroleptic multiple-stranded (HLMS) metallosupramolecules are summarized. To construct HLMS metallosupramolecules, one type of the multitopic ligand can be employed for structural completion of the multi-nuclear clusters, while another type of the multitopic ligand can be utilized to construct multiple strands. Most HLMS metallosupramolecules adopt helical geometries and have high molecular symmetry, which can be key factors for structural generation.
저자 TRANMINHNGOC, 유효종
소속 한양대
키워드 heteroleptic; multiple-stranded; metallosupramolecule
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