| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Arrangement of the Block Copolymers Microdomains Confined at Hemi-sphere Walls |
| 초록 |
The arrangement of the microdomains of polystyrene-block-poly(methyl methacrylate) copolymer (PS-b-PMMA) confined at hemi-sphere walls was investigated by scanning and transmission electron microscopy. The hemi-spherical confinement was achieved by using anodic aluminum oxide (AAO) template. The wall surface was modified by thin layers grafted by PS, PMMA, and PS-ran-PMMA copolymer. When the diameter of AAO is commensurate with the bulk lamellar spacing (L0) of PS-b-PMMA, the concentric rings consisting of PS and PMMA are observed. However, the commensurability was not satisfied, we found various interesting morphologies which have not been reported in the literature. The observed microdomain arrangement was compared with theoretical predictions. |
| 저자 |
배두식1, 변진석1, 전금혜1, Hiroshi Jinnai2, 허준3, 김진곤1
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| 소속 |
1포항공과대, 2KIT, 3연세대 |
| 키워드 |
Block copolymer; confinement; PS-b-PMMA
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| E-Mail |
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