| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of potassium phthalimide-initiated polymerization of ethylene oxide and its chain-end functionalization |
| 초록 |
Ring opening polymerization of ethylene oxide (EO) was performed successfully using potassium phthalimide as an initiator via anionic mechanism. Initiator was dissolved in purified DMSO in the round bottom flask. All the reactions were performed under high vacuum. Practically, the polymerization of EO was carried out in DMSO at 60oC for 12 h, followed by precipitation in excess diethyl ether. The resulting polymer was used for the synthesis of block copolymer using N-phenylmaleimide. Deimidation of the block copolymer was performed using hydrazine monohydrate in DMSO at 120oC under acidic conditions (pH=4.5) resulting in the generation of α-amino-PEO-based block copolymer carrying cyclic hydrazide. In this presentation, we will report on the preliminary results. |
| 저자 |
시디크 아부 바카1, 김윤2, 양세라2, 김성우2, 이유라2, 김현준2, 이재열2, 강호정2, 김정안3
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| 소속 |
1경희대, 2Kyung Hee Univ., 3professor |
| 키워드 |
anionic polymer; PEG/PEO; Functional polymer; thiol/Amine
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| E-Mail |
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