화학공학소재연구정보센터
학회 한국재료학회
학술대회 2017년 가을 (11/15 ~ 11/17, 경주 현대호텔)
권호 23권 2호
발표분야 G. 나노/박막 재료 분과
제목 Hydrogen Gas Sensor using Pd-decorated Al2O3/SrTiO3 heterostructure
초록 Two-dimensional electron gas (2DEG) at the interface of oxide heterostructure attracted attentions due to their unique physical properties, e.g., on epitaxial LaAlO3/single crystalline SrTiO3 heterostructure. Recently, we reported 2DEG at the interface of amorphous Al2O3/single crystalline SrTiO3 heterostructure by using atomic layer deposition (ALD) technique. The origin is a generation of oxygen vacancies on the SrTiO3 surface due to redox reaction between Al2O3 and SrTiO3 interface during the Al2O3 ALD process. The electrical properties were comparable to epitaxial LaAlO3/SrTiO3 heterostructure with high electron densities of 1013~1014/cm2, which densities are 100 times higher than conventional semiconductor heterojunctions.
In this work, we demonstrate high-performance hydrogen gas sensors based on 2DEG at Al2O3/SrTiO3 heterostructure. Pd is decorated on top of the Al2O3/SrTiO3 heterostructure and reacts with hydrogen to form PdHx, which changes the resistance of the 2DEG. The electrons are confined in a few nanometer at the interface of Al2O3/SrTiO3, which exhibited high sensitivity due to its two-dimensional properties. The operation principle will be discussed at the presentation.
저자 Sung Min Kim1, Hye Ju Kim2, Sang Woon Lee1
소속 1Department of Physics and Department of Energy Systems Research, 2Ajou Univ.
키워드 Hydrogen Gas Sensor;  Two-dimensional electron gas (2DEG); Oxide heterostructure
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