화학공학소재연구정보센터
학회 한국재료학회
학술대회 2018년 가을 (11/07 ~ 11/09, 여수 디오션리조트)
권호 24권 2호
발표분야 8. 하이브리드 광/전자 기능성 소재기술(Hybrid optic-electronic functional materials)-오거나이저: 김연상 교수(서울대)
제목 Paper/Textile Electrodes Using Inorganic Nanoparticle Assembly
초록 Paper/Textile Electrodes Using Inorganic Nanoparticle Assembly

Yongmin Ko, Cheong Hoon Kwon, Yongkwon Song, and Jinhan Cho*

Department of Chemical and Biological Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul 136–713, Republic of Korea

*E-mail: [email protected]  

Abstract

The effective implantation of conductive and charge storage materials into flexible frames has been strongly demanded for the development of flexible supercapacitors. Here, we introduce metallic cellulose paper-based supercapacitor electrodes with excellent energy storage performance by minimizing the contact resistance between neighboring metal and/or metal oxide nanoparticles using an assembly approach, called ligand-mediated layer-by-layer assembly. This approach can convert the insulating paper to the highly porous metallic paper with large surface areas that can function as current collectors and nanoparticle reservoirs for supercapacitor electrodes. Moreover, we demonstrate that the alternating structure design of the metal and pseudocapacitive nanoparticles on the metallic papers can remarkably increase the areal capacitance and rate capability with a notable decrease in the internal resistance. The maximum power and energy density of the metallic paper-based supercapacitors are estimated to be 15.1 mW•cm−2 and 267.3 μW•h•cm−2, respectively, substantially outperforming the performance of conventional paper or textile-type supercapacitors.
저자 조진한, 고용민, 권정훈, 송용권
소속 고려대
키워드 <P>층상자기조립; 종이 전극; 단분자; 나노입자</P>
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