화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 학생우수논문발표(박사과정)
제목 Fabrication of co-continuous nanoporous polymer thin film
초록 Nanoporous materials with a pore size ranging from 1 nm to 100 nm have demonstrated applications in a number of multidisciplinary fields. In particular, the large internal surface area of nanoporous materials optimizes their use as a functional structure which absorbs or interacts with atoms, ions, and molecules. In this study, we first demonstrated co-continuous phase separation morphology with a nanometer scale using spinodal decomposition of polymer blend, which is homopolymer /random copolymer blend with mild interaction strength. Selective extraction of random copolymer led to co-continuous nano-channel, but thin wetting layer of the homopolymer-rich phase at the surface due to lower surface energy of homopolymer resulted in closed surface. Next, UV ozone surface treatment was introduced to achieve open surface of nanoporous thin film as well as increasing wettability. It was confirmed that the nanoporous film can be used as a template for interpenetrating network morphology.
저자 이희선, 허규용
소속 한국화학(연)
키워드 Homopolymer-copolymer blend; Spinodal decomposition; Nanoporous thin film; UV ozone; Surface treatment
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