| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
(국제협력) 우수 외국인 연구자 세션 |
| 제목 |
PdO@SNP: A Competent Green Heterogeneous Approach to One-pot Catalytic Decarbonylation of Primary Alcohols |
| 초록 |
Palladium oxide doped over silica nanoparticles (PdO@SNPs) heterogeneous system was proved as a facile green approach for direct dehydrogenative decarbonylation of an ample series of primary alcohols. The catalyst was considered as to support two successive conversions in one-pot without any co-catalyst at relatively low temperature. Optimization of the reaction of 2-naphthalenemethanol to naphthalene was followed by the decarbonylation of variety of substrates demonstrating a good to excellent selectivity and yield of products. ICP-AES analysis revealed no leaching of metal in the reaction vessel ensuring a robust mechanical stability and reusability of PdO@SNP nanocatalyst. |
| 저자 |
Irshad Mobina, 김정원
|
| 소속 |
강원대 |
| 키워드 |
PdO@SNP; dehydrogenative decarbonylation; one-pot; mechanical stability
|
| E-Mail |
|
