화학공학소재연구정보센터
학회 한국재료학회
학술대회 2007년 봄 (05/10 ~ 05/11, 무주리조트)
권호 13권 1호
발표분야 에너지 환경재료
제목 Perspectives of Nanopores on The Stems of Nanotubes
초록 Experimental and theoretical approaches are used to determine hydrogen storage mechanisms in nanopores of multi-walled carbon nitride nanotubes (MWCNNT). First, we produce ~0.6nm pores on the stems of MWCNNTs by plasma-enhanced chemical vapour deposition. Next, thermal desorption spectra were measured and obtained two different peaks. This is explained by hydrogen desorption barriers of 0.36 to 0.50 eV attributed to two different types of ~0.6nm pores. Moreover, H2 adsorption between complete interlayers is found to be endothermic by 1.27 eV. In this respect, open channels and ~0.6nm pores on MWCNNTs are considered to provide the route for reversible hydrogen storage.
저자 Se Yun Kim1, Hyun Seok Kim2, Jeung Ku Kang1
소속 1Department of Materials Science and Engineering, 2Korea Advanced Institute of Science and Technology
키워드 MWCNNT
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