| 학회 |
한국화학공학회 |
| 학술대회 |
2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
| 권호 |
20권 2호, p.1643 |
| 발표분야 |
에너지 |
| 제목 |
Application of mesoporous bimetallic NiCu-CeO2 oxide as a catalyst for the high temperature water-gas shift reaction |
| 초록 |
Mesoporous bimetallic NiCu-CeO2 catalysts have been designed and applied to high temperature water gas shift reaction (HT-WGS). We optimized the loading of nickel and copper on mesoporous ceria to obtain highly active and selective catalysts for HT-WGS. Among the catalysts with various nickel and copper loading values, 6%Ni24%Cu-CeO2 catalyst exhibited not only the highest catalytic activity and selectivity but also remarkable stability. The high activity of the catalyst is due to the mesoporous architecture which provides more accessible active sites for the HT-WGS. The detailed studies on the composition and mesoporosity of the catalysts were performed by using powder X-ray diffraction (XRD), Small angle x-ray scattering (SAXS), N2-adsorption/desorption and H2 temperature-programmed reduction (TPR) techniques to understand the role of bimetallic oxide (NiCu-oxide) in the enhancement of catalytic activity for the HT-WGS. |
| 저자 |
JHA AJAY, 정대운, 한원비, 나현석, 심재오, 장원준, 이열림, 전경원, 김학민, 노현석
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| 소속 |
연세대 |
| 키워드 |
Mesoporous; Bimetallic; High temperature water gas shift; NiCu-CeO2
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| E-Mail |
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| 원문파일 |
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