| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electrochemical study of [Ni(II)(CN)4]2-complexinthe1-butyl-3-methylimidazolium hexafluorophosphate RTIL |
| 초록 |
The study of metal ions in RTIL is a booming area in electrochemistry field. In particularly sufficient redox behavior of metal ions can act as mediators in the RTIL electrolyte to synthesis the organic compounds in green way. But selection of suitable mediator is a challenging role for the green organic synthesis. Apart from metal ions, many metal complexes such as Ni(Salen) , Co(Salen), Ni(byp) have been widely investigated in the RTIL their solubility restricts to use in industrial applications. Cyanide ligand with metalation is a simple and strongest especially highly soluble nature. Based on this idea we have investigated reduction behavior of [Ni(CN)4]2- complex in the 1-butyl-3-methylimidazolium hexa fluoro phosphate ([bmim]PF6) RTIL and the Ni complex were analyzed to derive electrochemical parameters towards industrial applications. |
| 저자 |
G. MUTHURAMAN, K.Kannan, 문일식
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| 소속 |
순천대 |
| 키워드 |
RTIL; bmim pf6 IL; [Ni(CN)4]2- complex; redox behavior.
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| E-Mail |
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