| 학회 | 한국화학공학회 |
| 학술대회 | 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터) |
| 권호 | 19권 1호, p.945 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Hydrogen Production by Steam Reforming of Glycerol over Spherical Ni-based modified Catalyst |
| 초록 | During the synthesis of biodiesel from biomass, about 10% of glycerol was formed as a main byproduct. Increasing biodiesel production has resulted in over-production of glycerol. Steam reforming (SR) of glycerol is one of the common processes to produce hydrogen or synthesis gas. And Ni-based catalysts are widely used in SR of glycerol. In this study, the structured M-Ni/γ-Al2O3, (M : K, Ca, Sr) catalyst were prepared by dry impregnation method. All catalysts have been employed for SR under at atmospheric pressure, 800 °C with gas hourly space velocity (GHSV) of 10,000 h-1 and feed molar ratios of Steam/Carbon=3. The prepared catalysts before and after the reaction were characterized by N2 physisorption, XRD, TPR, TGA, SEM-EDX, and TEM techniques. It was found that the addition of alkali promoter on Ni/γ-Al2O3 inhibited methane formation in the SR of glycerol under the tested conditions. Moreover, the presence of alkali metal on Ni/γ-Al2O3 also promoted the stability of the catalyst through suppression of coke formation. |
| 저자 | 김승훈, 양은혁, Kannapu Hari Prasad Reddy, 이윤주, 문동주 |
| 소속 | 한국과학기술(연) |
| 키워드 | Glycerol Steam Reforming |
| 원문파일 | 초록 보기 |
