화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Synthesis and supercapacitive properties of electrodeposited polyaniline composite electrode on acrylonitrile-butadiene rubber as a flexible current collector
초록 Flexible sheets consisting of acrylonitrile-butadiene rubber (NBR) and vapor-grown carbon fiber (VGCF) are newly prepared varying the composition (VGCF 20–30 wt.%) for use as a current collector of supercapacitor electrodes. The as-prepared VGCF/NBR is then electrodeposited by aniline using a potentiodynamic cyclic voltammetry to yield a polyaniline (PANI)/VGCF/NBR composite electrode. It is confirmed that the electrical conductivity of VGCF/NBR current collector can be enhanced as the content of VGCF increases. Cyclic voltammetry result for the PANI/VGCF/NBR composites shows that the sample with 30 wt.% VGCF achieves a maximum specific capacitance (271.8 F g−1) at 5 mV s−1 and also reaches a superior specific capacitance at high scan rates. Such supercapacitor performance is possibly originated from the synergistic effect consisting of higher polarity of nitrile groups in NBR, conducting pathway of VGCF, and electroactive property of PANI.
저자 AlfredMadzamuse1, Jang Myoun Ko1, Sang Hern Kim1, Hyun Woo Cho1, Yong Min Lee1, Kwang Man Kim2, Jong Huy Kim3
소속 1Hanbat National Univ., 2Electronics and Telecommunications Research Institute (ETRI), 3Korea Institute of Energy Research
키워드 Acrylonitrile-butadiene rubber; Vapor-grown carbon fiber; Polyaniline; Flexible current collector; Supercapacitor
E-Mail