화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 (석유화학윤활유) 석유화학 촉매 및 환경친화형 소재 개발
제목 Synthesis of polylactide-containing block copolymers and derivation of porous polymers
초록 Polymers derived from renewable resources such as biomass has recently attracted significant attention as an appealing solution to sustainability issues of polymeric materials. Polylactide (PLA) is one of the most popular and commercially available sustainable polymers typically synthesized by ring opening transesterification polymerization (ROTEP) of a cyclic lactide monomer derived from sugar. By combining ROTEP with other controlled polymerization techniques, it is possible to integrate PLA into a block architecture consisting of highly distinct polymer blocks and utilize the resulting block polymers into advanced applications. In this talk I will focus on synthesis of PLA-containing block polymers as precursors to well-defined nanoporous polymers by exploiting high degradability of PLA under basic condition. I will present synthetic routes to PLA-containing block polymers by combining ROTEP and reversible addition-fragmentation chain transfer (RAFT) polymerization and demonstrate how well-defined nanoporous polymers can be derived from the precursor block polymers.
저자 서명은
소속 한국과학기술원
키워드 polylactide; block copolymer; porous polymer
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