화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 봄 (04/22 ~ 04/23, 대구 EXCO)
권호 16권 1호, p.615
발표분야 열역학
제목 An Analytical Expression for the Nonrandomness in Lattice Fluid Equation of State
초록 The in the common lattice fluid framework the contribution functions are usually divided into a random and nonrandom part. In this work an analytical expression for the nonrandomness of r-mer fluids is presented. This approach leads to an explicit expression for the local composition model. The resulting nonrandomness factors are explicit and yield higher degrees of free volume contributions that those obtained by Guggenheim's quasi chemical approach. A new equation of state is derived based on the proposed expression and applied to various pure components and mixtures.
저자 알렉산더, 유기풍
소속 서강대
키워드 nonrandomness; lattice fluid; equation of state
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